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Precise determination of stabilities of primary, secondary, and tertiary silicenium ions from kinetics and equilibria of hydride-transfer reactions in the gas phase. A quantitative comparison of the stabilities of silicenium and carbonium ions in the gas phase

✍ Scribed by Shin, Seung Koo; Beauchamp, J. L.


Book ID
119996519
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
944 KB
Volume
111
Category
Article
ISSN
0002-7863

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## Abstract The pyrolysis kinetics of primary, secondary, and tertiary β‐hydroxy ketones have been studied in static seasoned vessels over the pressure range of 21–152 torr and the temperature range of 190°–260Β°C. These eliminations are homogeneous, unimolecular, and follow a first‐order rate law.