UV spectra and kinetics for the reactions of alkyl and alkylperoxy radicals from methyl tert-butyl ether (MTBE) were studied in 1 atm of SF, by the pulse radiolysis-UV absorption technique. UV spectra for the radical mixtures were quantified from 215 to 340 nm. At 240 nm, a, = (2.6 f 0.4) X lo-l8 cm
Structure and Reactivity of the Radical Cations of Methyl tert-Butyl Ether in Condensed Phase: An ESR and Quantum Chemical Study
β Scribed by D. A. Tyurin; V. N. Belevskii
- Book ID
- 110314063
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 2001
- Tongue
- English
- Weight
- 129 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0018-1439
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The products of the reaction of the hydroxyl (OH) radical with methyl tert-butyl ether (MTBE) in NO,-air systems were identified and measured by Fourier transform infrared absorption spectroscopy and gas chromatography. The products observed, and their yields, were as follows: t-butyl formate, 76 ?
The ESR spectra of radical cations of cis-and trans-deealin have been recorded in different halocarbon matrices within the temperature range 4.2 IO 130 K. The ground-state structures of both isomers have been calculated using the UHF/MNDO technique and found to be 'As or ZB, for transdecalin+ and 'A