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Computer-assisted modeling of subtilisin enantioselectivity in organic solvents

✍ Scribed by Paul A. Fitzpatrick; Dagmar Ringe; Alexander M. Klibanov

Publisher
John Wiley and Sons
Year
1992
Tongue
English
Weight
754 KB
Volume
40
Category
Article
ISSN
0006-3592

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πŸ“œ SIMILAR VOLUMES

Effect of crown ethers on structure, sta
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✍ AngΓ©lica M. Santos; Michael Vidal; Yamaris Pacheco; Joel Frontera; Carlos BΓ‘ez; πŸ“‚ Article πŸ“… 2001 πŸ› John Wiley and Sons 🌐 English βš– 211 KB πŸ‘ 2 views

## Abstract Colyophilization or codrying of subtilisin Carlsberg with the crown ethers 18‐crown‐6, 15‐crown‐5, and 12‐crown‐4 substantially improved enzyme activity in THF, acetonitrile, and 1,4‐dioxane in the transesterification reactions of __N__‐acetyl‐L‐phenylalanine ethylester and 1‐propanol a

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Solvent effects on the catalytic activity of subtilisin suspended in organic solvents
✍ Teresa CorrΓͺa de Sampaio; Rui B. Melo; Teresa F. Moura; Stefan Michel; Susana Ba πŸ“‚ Article πŸ“… 1996 πŸ› John Wiley and Sons 🌐 English βš– 907 KB

We studied a model transesterification reaction catalyzed by subtilisin Carlsberg suspended in toluene, n-hexane, diisopropyl ether, and mixtures of these solvents. To account for solvent effects due to differences in water partitioning between the enzyme and the bulk solvents, we measured water sor