l7re in situ alcoholysis of Ph@NSiMe, in the presence of anhydrous halides of zinc, cadmium and mercury results in the formation of a range of co-ordination complexes of triphenylphosphinimine, Ph,P=NH (L). The complexes formed were of three types: i) the trans dimers [(MX2L)2], ii) the cyclic dimer
Complex formation of zinc, cadmium, and mercury with penicillamine
β Scribed by Runar Strand; Walter Lund; Jan Aaseth
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 522 KB
- Volume
- 19
- Category
- Article
- ISSN
- 0162-0134
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Abstract A number of compounds of general formula M(PPO)~__n__~X~2~ are described, the metal ion being Zn(II), Cd(II) and Hg(II) and the anions Cl^β^, Br^β^, I^β^, NO~3~^β^, ClO~4~^β^ and NCS^β^; PPO stands for 2,5βdiphenyloxazole and __n__ = 1, 2, 4. The complexes are prepared by reaction of t
Assignments of v,$SMS) and v~SMS) for the complexes iPI( (M = Zn, Cd, Hg; R = Et, Bu') and Hg(SMe)z from infrared and Raman spectroscopy are reported. Comparison of frequencies for the complex Hg(SBuf)2 containing four-coordinate mercury with those of Hg(SRlz (R = Me, Et) containing twocoordinate me