Metal-sulphur stretching frequencies and structures of complexes of zinc, cadmium, and mercury with thiols

✍ Scribed by A.J. Canty; R. Kishimoto; G.B. Deacon; G.J. Farquharson

• Publisher: Elsevier Science
• Year: 1976
• Tongue: English
• Weight: 505 KB
• Volume: 20
• Category: Article
• ISSN: 0020-1693
• DOI: 10.1016/s0020-1693(00)94110-0

✦ Synopsis

Assignments of v,$SMS) and v~SMS) for the complexes iPI( (M = Zn, Cd, Hg; R = Et, Bu') and Hg(SMe)z from infrared and Raman spectroscopy are reported. Comparison of frequencies for the complex Hg(SBuf)2 containing four-coordinate mercury with those of Hg(SRlz (R = Me, Et) containing twocoordinate mercury permits assignment of a polymeric structure with linear coordination for the 1:I complex of Hg(l/l with 2,3dimercaptopropanol (British anti-Lewisire).