The high resolution infrared spectra of 12 CD 3 I and 13 CD 3 I molecules have been measured in the region of the CD 3 deformation bands n 2 and n 5 using a Fourier transform spectrometer. The coupled band system n 2 , n 5 , and 2n 3 has been analyzed by taking into account the Coriolis resonances n
Complement to the analysis of the ν5 band of 12CD3H
✍ Scribed by Janine Dupre-Maquaire
- Book ID
- 103203393
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 450 KB
- Volume
- 101
- Category
- Article
- ISSN
- 0022-2852
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📜 SIMILAR VOLUMES
## Abstract The ν~5~ Raman band of CH~3~CD~3~ was photographed with a resolution of about 0.4 cm^−1^ and analysed by an iterative method, in which the peak wavenumbers of the observed and computed contours are compared directly. Precise values for ν~0~ and Δ__B__ were obtained, whereas it only coul
The Raman spectrum of the Coriolis interacting u2, us bands of CD,CI was recorded with a resolution of cu 0.6 cm-'. Using the vibrational-rotational parameters of Yamada and Hirota, a computer simulation of the Raman contour was performed, yielding relative values of Raman polarizability derivatives
A total of 6071 transition wavenumbers of the 2 , 3 , 5 , and 6 fundamental bands of H 3 13 CF and 1689 frequencies of the rotational transitions in the v 2 ϭ 1, v 3 ϭ 1, v 5 ϭ 1, and v 6 ϭ 1 vibrational states have been fitted simultaneously by taking into account various Coriolis interactions, l-t
A total of 4892 transition wavenumbers of the 2 , 3 , 5 , and 6 fundamental bands of H 3 12 CF and 1469 frequencies of the rotational transitions in the v 2 ϭ 1, v 3 ϭ 1, v 5 ϭ 1, and v 6 ϭ 1 vibrational states have been fitted simultaneously by taking explicitly into account various Coriolis intera