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Raman polarizabilities of the ν2, ν5 bands of CD3Cl

✍ Scribed by R. Escribano; M. García Hernández; M. Mejías; S. Brodersen

Publisher
John Wiley and Sons
Year
1985
Tongue
English
Weight
353 KB
Volume
16
Category
Article
ISSN
0377-0486

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✦ Synopsis

The Raman spectrum of the Coriolis interacting u2, us bands of CD,CI was recorded with a resolution of cu 0.6 cm-'. Using the vibrational-rotational parameters of Yamada and Hirota, a computer simulation of the Raman contour was performed, yielding relative values of Raman polarizability derivatives for these bands. By comparison with the absolute intensity measurement of Orza et al., absolute values of the Raman polarizabilities were obtained. The sign of the Raman intensity perturbation was found to be negative.

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