𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The ν2 + ν3 − ν2 Band of NH+3

✍ Scribed by T.R. Huet; Y. Kabbadj; C.M. Gabrys; T. Oka


Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
349 KB
Volume
163
Category
Article
ISSN
0022-2852

No coin nor oath required. For personal study only.

✦ Synopsis


The (\nu_{2}+\nu_{3}-\nu_{2}) hot band of (\mathrm{NH}{3}^{+}\left(\dot{X}^{2} A{2}^{\prime \prime}\right)) has been observed on the absorption spectrum recorded by using a difference frequency laser spectrometer combined with the velocity modulation technique in the region between 3500 and (2900 \mathrm{~cm}^{-1}). The molecular ions were produced in the positive column of a glow discharge with a gas mixture of (\mathrm{N}{2} / \mathrm{H}{2} / \mathrm{He}) in a ratio around (1 / 1 / 100). From the observed spectrum, the band origin was determined (\left(\nu_{0}=3371.5607(21) \mathrm{cm}^{-1}\right)) and the rotational structure characterized up to (N, K=10, N-4). A symmetric rotor Hamiltonian with (A_{1}-A_{2}) splittings and (/) resonance was used for the analysis and the spin-rotation constants were determined. The values obtained for the centrifugal distortion constants of both states do not satisfy the planarity relations. This fact is interpreted as an evidence for the presence of an (x-y) Coriolis interaction between the (\nu_{2}) and the (\nu_{4}) states, in agreement with theoretical predictions by Kraemer and Spirko (J. Mol. Spectresc. 153, 276-284, 1992). The lack of experimental observation on (\nu_{4}) prevented a full treatment of the perturbation. (c. 1994 Academic Press. Inc.


📜 SIMILAR VOLUMES


Absolute Intensity of the NH3 ν2 Band
✍ Mike Fabian; Koichi M.T. Yamada 📂 Article 📅 1999 🏛 Elsevier Science 🌐 English ⚖ 224 KB

Absolute line intensities of NH 3 in the 2 band were measured for a number of rovibrational lines using a high-resolution Fourier transform infrared spectrometer. The transition dipole moments calculated from the absolute intensities showed significant and systematic deviations from the usual rotati

H2-Broadening Coefficients in the ν4 Ban
✍ J.-P Bouanich; H Aroui; S Nouri; A Picard-Bersellini 📂 Article 📅 2001 🏛 Elsevier Science 🌐 English ⚖ 157 KB

H 2 -broadening coefficients have been measured for 66 rovibrational lines of NH 3 at room temperature in the P P and R P branches of the ν 4 band in the range 1470-1600 cm -1 , using a high-resolution Fourier transform spectrometer. The collisional widths are obtained by fitting Voigt profiles to t

Pressure Broadening and Shift of Some NH
✍ M. Fabian; R. Schieder; Koichi M.T. Yamada; G. Winnewisser 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 217 KB

Pressure-induced line broadening and line shift of four rovibrational transitions in the n 2 band of NH 3 and of two unassigned transitions at 10 mm were measured, using the wavelength-stabilized Cologne diode laser spectrometer with an improved recording system. Self-effects and foreign gas effects

Line Mixing Parameters in the ν4 Rovibra
✍ H. Aroui; M. Chevalier; M. Broquier; A. Picardbersellini; S. Gherissi; N. Legays 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 391 KB

Pressure broadening ( PB) linewidths and cross-relaxation parameters have been measured in the \(v_{4}\) rovibrational band of \(\mathrm{NH}_{3}\) (window region \(1450-1600 \mathrm{~cm}^{-1}\) ) using diode laser and Fourier transform (FT) spectrometers. The measurements were performed using \(\mat