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Combined Analysis of the Infrared Spectra of ν2, ν5, and 2ν3Bands of12CD3I and13CD3I

✍ Scribed by M. Koivusaari

Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
217 KB
Volume
183
Category
Article
ISSN
0022-2852

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✦ Synopsis

The high resolution infrared spectra of 12 CD 3 I and 13 CD 3 I molecules have been measured in the region of the CD 3 deformation bands n 2 and n 5 using a Fourier transform spectrometer. The coupled band system n 2 , n 5 , and 2n 3 has been analyzed by taking into account the Coriolis resonances n 2 /n 5 and 2n 3 /n 5 . Furthermore, l-type resonance effects played an important role in the analysis. As a result, the molecular constants for the states £ 2 Å 1, £ 5 Å 1, and £ 3 Å 2 including the resonance parameters describing the interactions between these energy levels have been obtained.

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