The high resolution infrared spectra of 12 CD 3 I and 13 CD 3 I molecules have been measured in the region of the CD 3 deformation bands n 2 and n 5 using a Fourier transform spectrometer. The coupled band system n 2 , n 5 , and 2n 3 has been analyzed by taking into account the Coriolis resonances n
Analysis of the Infrared Spectra of the Fundamentals ν3and ν6of12CD3I and13CD3I
✍ Scribed by M. Koivusaari
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- English
- Weight
- 175 KB
- Volume
- 185
- Category
- Article
- ISSN
- 0022-2852
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✦ Synopsis
The high-resolution infrared spectra of the lowest fundamental bands n 3 and n 6 of 12 CD 3 I and 13 CD 3 I have been measured using a Fourier transform spectrometer. The bands are analyzed on one hand by taking into account the Coriolis resonance n 3 /n 6 and on the other hand without this Coriolis effect. The molecular constants obtained for the two vibration modes are introduced and a discussion of the influence of the Coriolis interaction to the parameter set is shortly outlined.
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