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Competitive chlorination–dehydrochlorination of 1,1,1,2-C2H2Cl4

✍ Scribed by J. Olbregts

Publisher
John Wiley and Sons
Year
1979
Tongue
English
Weight
367 KB
Volume
11
Category
Article
ISSN
0538-8066

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✦ Synopsis

Abstract

The competitive photochlorination and chlorine photosensitized dehydrochlorination of 1,1,1,2‐C~2~H~2~Cl~4~ have been studied over the temperature range of 349.4–404.5 K after less than 1% conversion. The results are discussed and a value of
is proposed for the reaction
This result, combined with existing thermochemical data, indicates that there is no evidence of an activation energy for the addition of a Cl atom on the most chlorinated carbon in trichloroethylene: in that case the selectivity of the addition of Cl on the less chlorinated carbon should not depend on temperature.

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