Comparison of the rate constants for VV energy transfer in the gas and liquid phases
β Scribed by P.A. Madden; F. van Swol
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 952 KB
- Volume
- 112
- Category
- Article
- ISSN
- 0301-0104
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Reactions of ozone with simple olefins have been studied between 6 and 800 mtorr total pressure in a 220-m3 reactor. Rate constants for the removal of ozone by an excess of olefin in the presence of 150 mtorr oxygen were determined over the iemperature range 280 to 360" K by continuous optical absor
## Gas -phase azulene molecules were prepared with 17200 cm-' vibrational energy in the Su state by laser excitation of the St state and subsequent internal conversion. Rates of vibrational energy removal (for several collision partners) were determined from the decay of the CHstretch fluorescence
## Abstract The reactions of the biogenic organic compounds isoprene and 2βmethylβ3βbutenβ2βol (MBO) with ozone have been investigated under controlled conditions for pressure (atmospheric pressure) and temperature (293 Β± 2 K), using FTIR spectrometry. CO was added to scavenge hydroxyl radical form
Rate constants for vibrational energy transfer have been measured in the system N2( v= 1) +CO( u= 0) as a function of energy mismatch by using isotopic derivatives of N2 and of CO. These rate constants have been determined both in the gas phase and in liquid argon solution at 8 5 K. For non-resonant
## Abstract An analysis is made of relationships to be expected between the enthalpies and entropies of reactions carried out in the gas and liquid phases, assuming ideal thermodynamic behavior of the components. The results of the analysis are compared with experimental results reported in the lit