✦ LIBER ✦

Absolute rate constants for the gas-phase ozonolysis of isoprene and methylbutenol

✍ Scribed by N. Klawatsch-Carrasco; J. F. Doussin; P. Carlier

Publisher: John Wiley and Sons
Year: 2004
Tongue: English
Weight: 80 KB
Volume: 36
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.10175

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

The reactions of the biogenic organic compounds isoprene and 2‐methyl‐3‐buten‐2‐ol (MBO) with ozone have been investigated under controlled conditions for pressure (atmospheric pressure) and temperature (293 ± 2 K), using FTIR spectrometry. CO was added to scavenge hydroxyl radical formation during the ozonolysis experiments. Reaction rate constants were determined by absolute rate technique, by measuring both ozone and the organic compound concentrations. The measured values were k~1~ = (1.19 ± 0.09) × 10^−17^ cm^3^ molecule^−1^ s^−1^ for the reaction between ozone and isoprene and k~2~ = (8.3 ± 1.0) × 10~−18~ cm^3^ molecule^−1^ s^−1^ for the reaction between ozone and MBO. © 2004 Wiley Periodicals, Inc. Int J Chem Kinet 36: 152–156 2004

📜 SIMILAR VOLUMES

Rate constants for the gas-phase β-myrce

Rate constants for the gas-phase β-myrcene + OH and isoprene + OH reactions as a function of temperature

✍ Ronald A. Hites; Andrew M. Turner 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 491 KB 👁 1 views

## Abstract Rate constants for the gas‐phase reactions of the hydroxyl radical with the biogenic hydrocarbons, β‐myrcene and isoprene, were measured using the relative rate technique over the temperature range 313–413 K and at ∼1 atm total pressure. OH was produced by the photolysis of H~2~O~2~, an

Rate coefficients for the gas-phase reac

Rate coefficients for the gas-phase reactions of OH radicals with methylbutenols at 298 K

✍ Takashi Imamura; Yumi Iida; Kinichi Obi; Ikue Nagatani; Kazumichi Nakagawa; Iuli 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 102 KB 👁 1 views

## Abstract The relative‐rate method has been used to determine the rate coefficients for the reactions of OH radicals with three C~5~ biogenic alcohols, 2‐methyl‐3‐buten‐2‐ol (__k__~1~), 3‐methyl‐3‐buten‐1‐ol (__k__~2~), and 3‐methyl‐2‐buten‐1‐ol (__k__~3~), in the gas phase. OH radicals were prod

Rate constants and activation energies f

Rate constants and activation energies for ozonolysis of isoprene methacrolein and methyl-vinyl-ketone in aqueous solution: Significance to the in-cloud ozonation of isoprene

✍ Thorvald Pedersen; Knud Sehested 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 224 KB 👁 2 views

Rate coefficients for the gas-phase reac

Rate coefficients for the gas-phase reaction of isoprene with NO3 and NO2

✍ Jeanette R. Stabel; Matthew S. Johnson; Sarka Langer 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 207 KB 👁 2 views

## Abstract Rate coefficients for the gas‐phase reaction of isoprene with nitrate radicals and with nitrogen dioxide were determined. A Teflon collapsible chamber with solid phase micro extraction (SPME) for sampling and gas chromatography with flame ionization detection (GC/FID) and a glass reacto

Rate constants for reactions of CH3O2 in

Rate constants for reactions of CH3O2 in the gas phase

✍ R.A. Cox; G.S. Tyndall 📂 Article 📅 1979 🏛 Elsevier Science 🌐 English ⚖ 189 KB

## Receiwd 16 Ma> 1979 MoIecuhr modulation spectrometry has been employed to mesure the rate constants for the reactions ofCHxO2 with HOz. NO2 and X0. A negnthe tcmpcraturc dependence is reported for the rextion nirh HO\_r. Product spectra are giwn for the reactions with lIOt and NO?\_

Absolute rate constants for the gas-phas

Absolute rate constants for the gas-phase reaction of OH radicals with cyclohexane and ethane at 295 K

✍ Ole J. Nielsen; Jette Munk; Palle Pagsberg; Alfred Sillesen 📂 Article 📅 1986 🏛 Elsevier Science 🌐 English ⚖ 289 KB

The absolute rate constants for the gas-phase H-atom abstraction by hydroxyl radicals from cyclohexane and ethane have been determined at room temperature. OH radicals were produced by pulse radiolysis of an H,O-Ar mixture, and the decay of OH was followed by monitoring the transient light absorpti