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Non-and near-resonant (vv) energy transfer between the isotopes of N2 and of CO in liquid Ar and in the gas phase at 85 k

✍ Scribed by H.T. Williams; S.V. Gwynne; C.J.S.M. Simpson

Publisher: Elsevier Science
Year: 1987
Tongue: English
Weight: 329 KB
Volume: 138
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(87)80348-2

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✦ Synopsis

Rate constants for vibrational energy transfer have been measured in the system N2( v= 1) +CO( u= 0) as a function of energy mismatch by using isotopic derivatives of N2 and of CO. These rate constants have been determined both in the gas phase and in liquid argon solution at 8 5 K. For non-resonant processes we find /cL = ko; for the nearest to resonant system we find kL < ko. This result is considered to arise because long range forces important in near-resonant energy transfer operate to a lesser extent in the liquid phase.

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