𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Comparative DFT and HF-MP2 study on structure, relative stabilities and rotational barriers of end-on (η1) and side-on (η2) (PH3)2Pd HPPH model complexes

✍ Scribed by N. Russo; M. Toscano; A.L. Rizopoulos; M.P. Sigalas


Book ID
108328669
Publisher
Elsevier Science
Year
1998
Tongue
English
Weight
354 KB
Volume
273
Category
Article
ISSN
0020-1693

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


Lewis Adducts of the Side-On End-On Dini
✍ Felix Studt; Bruce A. MacKay; Samuel A. Johnson; Brian O. Patrick; Michael D. Fr 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 334 KB 👁 1 views

## Abstract Reaction of the side‐on end‐on dinitrogen complex [{(NPN)Ta}~2~(μ‐H)~2~(μ‐η^1^:η^2^‐N~2~)] (1; in which NPN=(PhNSiMe~2~CH~2~)~2~PPh), with the Lewis acids XR~3~ results in the adducts [{(NPN)Ta}~2~(μ‐H)~2~(μ‐η^1^:η^2^‐NNXR~3~)], XR~3~=GaMe~3~ (2), AlMe~3~ (3), and B(C~6~F~5~)~3~ (4). Th

Structural studies on chiral (π-Allyl)Pd
✍ Paul S. Pregosin; Renzo Salzmann 📂 Article 📅 1994 🏛 John Wiley and Sons 🌐 English ⚖ 426 KB

## Abstract The chiral (π‐allyl)Pd(II) complex [Pd(η^3^CH~3~CHCHCH~2~)(__S, S__‐Chiraphos)]CF~3~SO~3~ was shown to exist in four isomeric forms (two diastereomeric and two geometric). Aspects of their three‐dimensional structures were elucidated using ^1^H, ^13^C and ^31^P one‐ and two‐dimensional