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Ab Initio and Experimental Studies on the Structure and Relative Stability of the cis -Hydride−η 2 -Dihydrogen Complexes [{P(CH 2 CH 2 PPh 2 ) 3 }M(H)(η 2 -H 2 )] + (M = Fe, Ru)

✍ Scribed by Bianchini, Claudio; Masi, Dante; Peruzzini, Maurizio; Casarin, Maurizio; Maccato, Chiara; Rizzi, Gian Andrea


Book ID
119958185
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
295 KB
Volume
36
Category
Article
ISSN
0020-1669

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Theoretical Studies on the Metathesis Pr
✍ Wai Han Lam; Guochen Jia; Zhenyang Lin; Chak Po Lau; Odile Eisenstein 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 330 KB

## Abstract Theoretical calculations on the metathesis process, [Tp(PH~3~)MR(__η__^2^‐HCH~3~)] → [Tp(PH~3~)M(CH~3~)(__η__^2^‐HR)] (M=Fe, Ru, and Os; R=H and CH~3~), have been systematically carried out to study their detailed reaction mechanisms. Other than the one‐step mechanism via a four‐cente