✦ LIBER ✦

Heterolytic H 2 Activation by Dihydrogen Complexes. Effects of the Ligand X in [M(X)H 2 {Ph 2 P(CH 2 ) 3 PPh 2 } 2 ] n + (M = Ru, Os; X = CO, Cl, H)

✍ Scribed by Rocchini, Eliana; Mezzetti, Antonio; Rüegger, Heinz; Burckhardt, Urs; Gramlich, Volker; Del Zotto, Alessandro; Martinuzzi, Paolo; Rigo, Pierluigi

Book ID: 126830996
Publisher: American Chemical Society
Year: 1997
Tongue: English
Weight: 289 KB
Volume: 36
Category: Article
ISSN: 0020-1669
DOI: 10.1021/ic9605579

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

NMR Studies of the Complexes trans-[M(η

NMR Studies of the Complexes trans-[M(η 2 -H 2 )(H)(Ph 2 PCH 2 CH 2 PEt 2 ) 2 ]X (M=Fe, X = BPh 4 ; M = Os, X = BF 4 ): Evidence for Unexpected Shortening of the H-H Bond

✍ Bautista, Maria; Earl, Kelly; Morris, Robert 📂 Article 📅 1988 🏛 American Chemical Society 🌐 English ⚖ 275 KB

Dihydrogen with Frequency of Motion Near

Dihydrogen with Frequency of Motion Near the 1 H Larmor Frequency. Solid-State Structures and Solution NMR Spectroscopy of Osmium Complexes trans -[Os(H ·· H)X(PPh 2 CH 2 CH 2 PPh 2 ) 2 ] + (X = Cl, Br)

✍ Maltby, Patricia A.; Schlaf, Marcel; Steinbeck, Martin; Lough, Alan J.; Morris, 📂 Article 📅 1996 🏛 American Chemical Society 🌐 English ⚖ 300 KB

DFT Investigation of the Potential of [H

DFT Investigation of the Potential of [H-M{(NHCH2CH2)3X}] Catalysts (M = Mo, Ru, Os; X = N, P) for the Reduction of N2 to NH3 by H2

✍ Markus Hölscher; Walter Leitner 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 327 KB 👁 1 views

Reversible CH Bond Activation Reactions

Reversible CH Bond Activation Reactions of the N-Heterocyclic Carbene Ligands in Ru(Ph2PCH2CH2CH2PPh2)(IMes)(CO)H2 and Ru(Ph2AsCH2CH2PPh2)(IMes)(CO)H2 (IMes=1,3-Dimesityl-1,3-dihydro-2H-imidazol-2-ylidene)

✍ Mark J. Chilvers; Rodolphe F. R. Jazzar; Mary F. Mahon; Michael K. Whittlesey 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 118 KB 👁 2 views

## Abstract Thermolysis of Ru(IMes)(dppp)(CO)H~2~ (1, IMes=1,3‐dimesityl‐1,3‐dihydro‐2__H__‐imidazol‐2‐ylidene; dppp=Ph~2~PCH~2~CH~2~CH~2~PPh~2~) in the presence of trimethylvinylsilane yields Ru(IMes')(dppp)(CO)H (2) resulting from intramolecular ArCH~2~–H CH bond activation of the __N__‐heterocy

Synthesis and Structure of Pd II Complex

Synthesis and Structure of Pd II Complexes Containing the C,C-Chelating Bis-Ylide Ligand [Ph 3 PC(H)] 2 CO. X-ray Crystal Structure of {Pd(μ-Cl){[C(H)PPh 3 ] 2 CO}} 2 (ClO 4 ) 2 ·CH 2 Cl 2

✍ Falvello, Larry R.; Fernández, Susana; Navarro, Rafael; Rueda, Angel; Urriolabei 📂 Article 📅 1998 🏛 American Chemical Society 🌐 English ⚖ 108 KB

Functionalized Metal Oxide Clusters: Syn

Functionalized Metal Oxide Clusters: Synthesis, Characterization, Crystal Structures, and Magnetic Properties of a Novel Series of Fully Reduced Heteropolyoxovanadium Cationic Clusters Decorated with Organic Ligands[MV IV6 O 6 {(OCH 2 CH 2 ) 2 N(CH 2 CH 2 OH)} 6 ]X (M = Li, X = Cl·LiCl; M = Na, X = Cl·H 2 O; M = Mg, X = 2Br·H 2 O; M = Mn, Fe, X = 2Cl; M = Co, Ni, X = 2Cl·H 2 O)

✍ Khan, M. Ishaque; Tabussum, Saadia; Doedens, Robert J.; Golub, Vladimir O.; O'Co 📂 Article 📅 2004 🏛 American Chemical Society 🌐 English ⚖ 283 KB