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Chelate-Size Effects on the Structures, Chemical Behavior, Properties, and Catalytic Activity of the New Palladium(II)−Allyl Complexes [Pd(η 3 -1-R 1 -C 3 H 4 ){FcCHN-CH 2 -(CH 2 ) n -NMe 2 }][PF 6 ] {Fc = (η 5 -C 5 H 5 )Fe(η 5 -C 5 H 4 ), n = 2 or 1, and R 1 = H or Ph}

✍ Scribed by Pérez, Sonia; López, Concepción; Bosque, Ramon; Solans, Xavier; Font-Bardía, Mercè; Roig, Anna; Molins, Elies; van Leeuwen, Piet W. N. M.; van Strijdonck, Gino P. F.; Freixa, Zoraida

Book ID
126320669
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
351 KB
Volume
27
Category
Article
ISSN
0276-7333

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## Abstract The preparation of a family of dinuclear monocyclopentadienyl imidoniobium and ‐tantalum complexes was achieved by two different synthetic routes. The diimido complexes [{M(Cp′)Cl~2~}~2~(μ‐1,__i__‐NC~6~H~4~N)] [Cp′ = η^5^‐C~5~H~4~SiMe~3~, M = Nb, __i__ = 4 (1); Cp′ = η^5^‐C~5~H~4~SiMe~3