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Communications - Components of Podophyllin. XX. The Absolute Configuration of Podophyllotoxin and Related Lignans.

✍ Scribed by Schrecker, A. W.; Hartwell, J. L.


Book ID
126062163
Publisher
American Chemical Society
Year
1956
Tongue
English
Weight
221 KB
Volume
21
Category
Article
ISSN
0022-3263

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The absolute configuration of cuauhtemon
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The absolute configuration of cuauhtemone, a eudesmane-type sesquiterpene isolated from Pluchea species (Asteraceae), has been revised from 1 to 2 by chemical correlation with (R)-(+)-2-methyl-1,2-butanediol 3 through the naturally occurring 2,3-epoxy-2-methylbutanoate derivative 4. The relative ste