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THE ABSOLUTE CONFIGURATION OF ROSENONOLACTONE AND RELATED DITERPENOIDS

✍ Scribed by Whalley, W. B.; Green, B.; Arigoni, D.; Britt, J. J.; Djerassi, Carl


Book ID
125966898
Publisher
American Chemical Society
Year
1959
Tongue
English
Weight
267 KB
Volume
81
Category
Article
ISSN
0002-7863

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The absolute configuration of cuauhtemone, a eudesmane-type sesquiterpene isolated from Pluchea species (Asteraceae), has been revised from 1 to 2 by chemical correlation with (R)-(+)-2-methyl-1,2-butanediol 3 through the naturally occurring 2,3-epoxy-2-methylbutanoate derivative 4. The relative ste