We have reported' that treatment of the quadricyclene I with catalytic Ph2(norbornadiene)2C12 or Bh2(CO) Cl in CHCl 4 2 3 gives the norbornadiene II as the product. However, Nelson, Gillespie and Hinzhave shown that treatment of I with
β¦ LIBER β¦
Cobalt(II) tetraphenylporphyrin-catalyzed isomerization of electronegative substituted quadricyclanes
β Scribed by Sadao Miki; Toshinobu Ohno; Hideaki Iwasaki; Zen-ichi Yoshida
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- French
- Weight
- 205 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0040-4039
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A Remarkable Stereocontrol During Cobalt(II) Chloride Catalyzed Opening of Cinnamoyl Epoxides with N-Substituted Anilines. -The stereochemistry of the ring cleavage is controlled by the para-substituent of the aromatic ring directly attached to the nitrogen of the aniline. para-Methoxy groups cause