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Cobalt(II) tetraphenylporphyrin-catalyzed isomerization of electronegative substituted quadricyclanes

✍ Scribed by Sadao Miki; Toshinobu Ohno; Hideaki Iwasaki; Zen-ichi Yoshida


Publisher
Elsevier Science
Year
1985
Tongue
French
Weight
205 KB
Volume
26
Category
Article
ISSN
0040-4039

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A Remarkable Stereocontrol During Cobalt(II) Chloride Catalyzed Opening of Cinnamoyl Epoxides with N-Substituted Anilines. -The stereochemistry of the ring cleavage is controlled by the para-substituent of the aromatic ring directly attached to the nitrogen of the aniline. para-Methoxy groups cause