Mechanistic differences between the Rh(I), Pd(II) and Ag(I) catalyzed isomerization of quadricyclanes

✍ Scribed by H. Hogeveen; B.J. Nusse

• Publisher: Elsevier Science
• Year: 1974
• Tongue: French
• Weight: 209 KB
• Volume: 15
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(01)82162-6

✦ Synopsis

We have reported' that treatment of the quadricyclene I with catalytic Ph2(norbornadiene)2C12 or Bh2(CO) Cl in CHCl 4 2 3

gives the norbornadiene II as the product. However, Nelson, Gillespie and Hinzhave shown that treatment of I with