A variety of aromatic and some aliphatic aldehydes are efficientlv transformed to the corresvondinq carboxvlic acid in presence of catalytic amount of Cobal: (II)-chloride, molecular oxyyen and acetic anhydride at room temperature. Phenolic aldehydes underyo acylatiue oxidation to give the correspon
Cobalt(II) ion catalyzed oxidation of o-substituted anilines with molecular oxygen
✍ Scribed by László I. Simándi; Sándor Németh; Nikos Rumelis
- Publisher
- Elsevier Science
- Year
- 1987
- Weight
- 239 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0304-5102
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Polyaniline supported Co01) acetate catalyses the oxidation of different alkenes in the presence of 2-methylpropanal under the oxygen atmosphere at ambient teonil)Cralllrc "l'hi~ t:;Jl~lly~,l t;all be icu~,cd I'~n t:l~xith~ti~ns with~ut .ny decline in its
The reactivity of complexes of triphos [CH3C(CH2PPh2J3] and CoC1, towards dioxygen has been investigated. Reaction of the pseudo-tetrahedral complex (q2-triphos)CoC12 (1) with dioxygen yields after work-up the mixed phosphane/phosphane oxide ligands triphosO and triphosO,. The novel ligand triphosO,