Cobalt-Mediated Aldol-Type Reactions
โ Scribed by Orsini, Fulvia
- Book ID
- 118070970
- Publisher
- American Chemical Society
- Year
- 1997
- Tongue
- English
- Weight
- 134 KB
- Volume
- 62
- Category
- Article
- ISSN
- 0022-3263
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๐ SIMILAR VOLUMES
## Abstract For Abstract see ChemInform Abstract in Full Text.
Despite diverse reaction types and synthetic applications of diazoketones, chemical involvement of this moiety in an aldol sense has not been reported. The facility with which intramolecular reactions of this type can occur is described herein: The diazoketone II was prepared by the method of Tarb
A pyridoxal-mediated abzyme system for aldol and retro-aldol reactions is demonstrated. Antibody lOH2 catalyzes the aldol and retro-aldol reactions of 4-acetamidobenzaldehyde and glycine to P-hydroxy cr.-amino acid, using pyridoxal S-phosphate as a cofactor.