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Aldol-type reactions of diazoketones

✍ Scribed by T.L. Burkoth


Book ID
104240207
Publisher
Elsevier Science
Year
1969
Tongue
French
Weight
164 KB
Volume
10
Category
Article
ISSN
0040-4039

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✦ Synopsis


Despite diverse reaction types and synthetic applications of diazoketones, chemical involvement of this moiety in an aldol sense has not been reported.

The facility with which intramolecular reactions of this type can occur is described herein:

The diazoketone II was prepared by the method of Tarbell and Price 3 from the keto acid I. 4 A 0.l.M methanolic solution of the crude diazoketone, when


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## Abstract For Abstract see ChemInform Abstract in Full Text.