CO(a3Π): rate coefficients for quenching by O(3P)
✍ Scribed by W. Felder; W. Morrow; R.A. Young
- Publisher
- Elsevier Science
- Year
- 1972
- Tongue
- English
- Weight
- 382 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0009-2614
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📜 SIMILAR VOLUMES
The quenching rate for 0('S) by 0(3P) has been calculated using the 02 ab initio potential enerm curve< of Michels. From these calculations, the form for the rate is estimated to be k = 1.0 X lo-" esp(-760 caI/R?) cm3 molec-\* set-'. 0('S) + 0(3P)+O(1D) f O('D)+ 0.255 eV, (1
## Abstract Measurements of the rate coefficient of the reaction (O^3^__P__) + NO~2~ → O~2~ + NO have been made at 296°K and 240°K, using the technique of NO~2~\* chemiluminescent decay. Values of 9.3 × 10^−12^ cm^3^ molec^−1^ sec^−1^ at 296°K and 10.5 × 10^−12^ cm^3^ molec^−1^ sec^−1^ at 240°K wer
The rate coefficients for the reaction of O(3P) with the biogenic hydrocarbons A3-carene, a-pinene, and isoprene have been measured using a direct method for the first time. O(3P) was generated from the pulsed photolysis of NO2 or 0 3 a t 308 nm, and measured by resonance fluorescence at 131 nm. Rat