✦ LIBER ✦

Rate coefficients for the reactions of O(3P) with selected biogenic Hydrocarbons

✍ Scribed by Suzanne E. Paulson; John J. Orlando; Geoffrey S. Tyndall; Jack G. Calvert

Publisher: John Wiley and Sons
Year: 1995
Tongue: English
Weight: 710 KB
Volume: 27
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550271005

No coin nor oath required. For personal study only.

✦ Synopsis

The rate coefficients for the reaction of O(3P) with the biogenic hydrocarbons A3-carene, a-pinene, and isoprene have been measured using a direct method for the first time. O(3P) was generated from the pulsed photolysis of NO2 or 0 3 a t 308 nm, and measured by resonance fluorescence at 131 nm. Rate coefficients at room temperature for the biogenics are similar: (3.4 -+ 0.6) X and (3.5 2 0.6) X lo-'' cm3 molec-' s-', for A3-carene, a-pinene, and isoprene, respectively. The rate coefficients for the reaction of O(3P) with NO2 and ethene were also measured with the same method, and these values are within 4% and 10% of the currently recommended values, respectively. The correlation between OH and 0(3P)-alkene reaction rate coefficients is updated and discussed.

📜 SIMILAR VOLUMES

Rate constants for the reactions of O(3P

Rate constants for the reactions of O(3P) with selected monoterpenes

✍ Dongmin Luo; John A. Pierce; Irina L. Malkina; William P. L. Carter 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 English ⚖ 543 KB

## ~~ ~ Rate constants for the gas-phase reactions of O(3P) atom with a series of rnonoterpenes have been determined at ambient temperature (ca. 302-309 K ) and atmospheric pressure using a relative rate technique Using the literature rate constants for O(3P) + isobutene, cis and trans-2-butene, 3

Discharge flow-chemiluminescence study o

Discharge flow-chemiluminescence study of the rate coefficients for O(3P) + CF2CCl2 and O(3P) + CF3CFCF2 reactions at 298 K

✍ M. A. Teruel; R. A. Taccone; S. I. Lane 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 93 KB 👁 2 views

The kinetics of the reactions O( 3 P) ϩ CF 2 "CCl 2 and O( 3 P) ϩ CF 3 CF "CF 2 were studied at room temperature in a discharge flow tube system. The overall rate constants based on the measured afterglow reactions were (3.10 Ϯ 0.40) ϫ 10 Ϫ13 and (3.00 Ϯ 0.60) ϫ 10 Ϫ14 cm 3 molecule Ϫ1 s Ϫ1 , respec

The rate coefficient for the reaction of

The rate coefficient for the reaction of O(3P) with CH3OOH at 297 K

✍ Ghanshyam L. Vaghjiani; A. R. Ravishankara 📂 Article 📅 1990 🏛 John Wiley and Sons 🌐 English ⚖ 489 KB 👁 1 views

The absolute second-order rate coefficient for the reaction, O(3P) + CH300H + products, was measured to be ki = (1.06 ? 0.26) x cm3 molec-' s-l at 297 K, where the quoted error is 2 a including precision and estimated systematic errors. The possible presence of (CH3CHp),0 in our sample of CH,OOH lea

Theoretical rate constant calculations f

Theoretical rate constant calculations for O(3P) with saturated hydrocarbons

✍ J. V. Michael; D. G. Keil; R. B. Klemm 📂 Article 📅 1983 🏛 John Wiley and Sons 🌐 English ⚖ 847 KB

Theoretical rate constants have been calculated for O(3P) with five saturated hydrocarbons, CH4, CzHs, C3H8, ~so-C~HIO, and neo-CsH12. The method of choice is bond energy-bond order (BEBO) with activated complex theory (ACT). Because the BEBO method is empirical, O(3P) + CH4 is evaluated first, and

Rate coefficients for the gas-phase reac

Rate coefficients for the gas-phase reaction of NO3 radicals with selected dihydroxybenzenes

✍ R. I. Olariu; I. Bejan; I. Barnes; B. Klotz; K. H. Becker; K. Wirtz 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 121 KB 👁 1 views

## Abstract Using a relative kinetic technique, rate coefficients have been determined at (298 ± 2) K and atmospheric pressure for the gas‐phase reactions of the NO~3~ radical with three vicinal dihydroxy aromatic compounds. The experiments were carried out in a 1080‐l quartz glass reactor at the B

Absolute rate constants for the reaction

Absolute rate constants for the reactions O(3P) atoms with HCl and HBr

✍ Raymond D. H. Brown; Ian W. M. Smith 📂 Article 📅 1975 🏛 John Wiley and Sons 🌐 English ⚖ 728 KB

## Abstract A flow tube method has been used to determine rate constants for the elementary reactions: equation image Oxygen atoms were produced by adding a small excess of NO to a stream of partially dissociated nitrogen, and their reaction with hydrogen halide was monitored by observing the int