Quenching and radiation rates of CO (a 3Π)
✍ Scribed by G.M. Lawrence
- Publisher
- Elsevier Science
- Year
- 1971
- Tongue
- English
- Weight
- 332 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0009-2614
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📜 SIMILAR VOLUMES
Potential energy calculations for the interaction of CO( a 'IT) with Hr( X 'C: ) are presented, both at the MC SCF level and with the inclusion of extensive configuration interaction. In C1, geometry, the lowest two 3BI surfaces exhibit a strongly avoided crossing. At the highest level of theory use
Collisional deactivation processes of the CO\* A 2TI( u= I ) state are investigated by a time-resolved laser-induced fluorescence technique.Theoverallquenchingrateconstantsaredeterminedtobe (9.lfl.O)xlO-", (1.3~0.1)~10-", (1.1~0.1)~10-9, (1.9+ 0.1 )X 10m9, and (1.5 kO.1) X 10m9 cm' molecule-' s-',
## Radiative lifetimes and quenching rates habe been measured for rotational levels of CS A 'r~(v = 0) throughout the region of perturbation by the a' 3p -(u = 10) state. The measured lifetimes reflect the extent of mi..ing with the a' 3~ state and from the unperturbed value oft = 171 + 10 ns the