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Cleavage of the C-C bond in derivatives of barenecarboxylic acids

✍ Scribed by L. I. Zakharkin; Yu. A. Chapovskii


Book ID
112419544
Publisher
Springer
Year
1964
Tongue
English
Weight
53 KB
Volume
13
Category
Article
ISSN
1573-9171

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Further developments in metal-catalysed
✍ HervΓ© Bricout; Jean-FranΓ§ois Carpentier; AndrΓ© Mortreux πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 French βš– 235 KB

The use of a catalytic amount of nickelbis (l,4-bis(diphenylphosphino)butatne) in DMF enables the activation of the C-C bond in dimethyl allylmalonate derivatives to proceed under rather smooth reaction conditions, without added nucleophile. Several examples like isomerization of substituted-allyl r