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Novel cleavage reaction of the C16–N17 bond in naltrexone derivatives

✍ Scribed by Hideaki Fujii; Satomi Imaide; Akio Watanabe; Toru Nemoto; Hiroshi Nagase

Publisher
Elsevier Science
Year
2008
Tongue
French
Weight
233 KB
Volume
49
Category
Article
ISSN
0040-4039

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## Abstract Sodiumthiophenoxide and sodiumphenylselenide react with __N__‐benzyl‐ and __N__‐hexyl‐di‐__p__‐toluenesulfonamides (**1** and **2**) __via__ displacement at the C‐atom to afford the corresponding organosulfides and selenides in yields of 68–96%. In contrast, sodium cyanide converts disu