**More than a dozen examples verify that ethers are cleaved regioselectively in very good yields by MeSiCl~3~/NaI in acetonitrile;** primary and secondary methyl‐, benzyl‐, trityl‐ and tetrahydropyranyl ethers directly afford the primary and secondary alcohols. In the case of __tert__‐alkylmethyl et
Cleavage of carbonoxygen bonds. Dimethylboron bromide. A new reagent for ether cleavage
✍ Scribed by Yvan Guindon; Christiane Yoakim; Howard E. Morton
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- French
- Weight
- 205 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
A general and efficient procedure for the cleavage of a cyclic ethers by the use of dimethylboron bromide is described.
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