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ChemInform Abstract: Lithium Tetrafluoroborate: A Mild and Efficient Reagent for the Cleavage of Dimethoxytrityl Ethers.

✍ Scribed by Anqi Chen; Yong Zheng; Xinfeng Zhou


Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis


Lithium Tetrafluoroborate: A Mild and Efficient Reagent for the Cleavage of Dimethoxytrityl Ethers.

-LiBF 4 is a mild and highly efficient reagent for the cleavage of Dmt ethers (I). Functional groups such as silyl, isopropylidene, ester and epoxide as well as nucleotide bonds are not effected.


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ChemInform Abstract: Iodotrimethylsilane
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Iodotrimethylsilane: A Mild and Efficient Reagent for the Reduction of Azides to Amines. -An efficient and chemoselective protocol for the reduction of azides using in situ prepared iodotrimethylsilane as a reducing agent is reported. The corresponding amines are formed in excellent yields. -