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cis-μ-1,4-Diphenyl-1,4-diphosphorinane-κ2P:P′-bis[pentacarbonylchromium(0)] deuterochloroform solvate

✍ Scribed by Fild, Manfred ;Krüger, Oana N. ;Silaghi-Dumitrescu, Ioan ;Thöne, Carsten ;Weinkauf, Andreas

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
467 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, [Cr 2 (C 16 H 18 P 2 )(CO) 10 ]ÁCDCl 3 , crystallizes with one CDCl 3 solvent molecule per formula unit, with the solvent molecule residing in a niche between the two phenyl rings. The crystal studied was an inversion twin. The crystal packing shows secondary C-HÁ Á ÁO interactions.

📜 SIMILAR VOLUMES

Bis(cis-1,4-diphenyl-1,4-diphosphacycloh
Bis(cis-1,4-diphenyl-1,4-diphosphacyclohexane-κ2P,P′)platinum(II) bis(tetrafluoridoborate)
✍ Morey, Tara S. ;Miller, Susie M. ;Helm, Monte L. 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 722 KB

The title complex, [Pt(C 16 H 18 P 2 ) 2 ](BF 4 ) 2 , possesses a crystallographically imposed center of symmetry occupied by a Pt II ion, which is coordinated by four P atoms from two 1,4diphenyl-1,4-diphosphacyclohexane ligands in a distorted square-planar geometry. ## Related literature The co

Bis{μ-1,4-bis[(diphenylphosphanyl)ethyny
Bis{μ-1,4-bis[(diphenylphosphanyl)ethynyl]benzene-κ2P:P′}bis[trans-diiodidopalladium(II)] chloroform trisolvate
✍ Chan, Wing Yan ;Baumgartner, Thomas ;Lough, Alan J. ;Manners, Ian 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 382 KB

The title compound, [Pd 2 I 4 (C 34 H 24 P 2 ) 2 ]Á3CHCl 3 , was obtained from the direct reaction of PdI 2 with 1,4-bis[(diphenylphosphanyl)ethynyl]benzene. The dimer complex molecule is centrosymmetric, with each Pd II atom in a slightly distorted square-planar coordination geometry. ## Related l