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1,3-Bis­(diphenyl­phosphino)propane-2κ2P,P′-dicarbonyl-1κ2C-chloro-2κCl-{μ-2,2′,2′′-nitrilo­triethanethiol­ato(3–)-1κ4N,S,S′,S′′:2κ2S,S′}iron(II)nickel(II) acetonitrile solvate

✍ Scribed by Duff, S. E. ;Hitchcock, P. B. ;Davies, S. C. ;Barclay, J. E. ;Evans, D. J.

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
428 KB
Volume
61
Category
Article
ISSN
1600-5368

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1,3-Bis­(diphenyl­phosphino)propane-2κ2P
1,3-Bis­(diphenyl­phosphino)propane-2κ2P,P′-{μ-2-[bis(2-mercaptoethyl)amino]­ethanesulfinato(3–)-1κ4N,S,S′,S′′:2κ2S,S′}chloro-2κCl-dinitroso-1κ2N-iron(II)nickel(II) acetonitrile hemisolvate
✍ Duff, S. E. ;Hitchcock, P. B. ;Davies, S. C. ;Barclay, J. E. ;Evans, D. J. 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 168 KB

Bis(diphenylphosphino) propane-2j 2 P,P 0 0 0 -{l-2-[bis(2-mercaptoethyl)amino]ethanesulfinato(3-)-1j 4 N,S,S 0 0 0 ,S 0 0 00 0 0 :2j 2 S,S 0 0 0 }chloro-2jCl-dinitroso-1j 2 Niron(II)nickel(II) acetonitrile hemisolvate

Tetrakis[2-(dimethylaminomethyl)phenyl]-
Tetrakis[2-(dimethylaminomethyl)phenyl]-1κC,2κC,3κC,4κC-hexa-μ-sulfido-1:2κ4S:S;1,4κ2S:S;2:3κ2S:S;3:4κ4S:S-tetratin(IV) chloroform solvate
✍ Varga, Richard A. ;Silvestru, Cristian 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 784 KB

The title compound, [Sn~4~(C~9~H~12~N)~4~S~6~]·CHCl~3~, consists of four [2-(Me~2~NCH~2~)C~6~H~4~]Sn units bridged by six S atoms along with a disordered solvent molecule. The cage-like structure has two four-membered Sn~2~S~2~ rings linked by two S atoms in an Sn~4~S~6~ skeleton. The asymmetry of t