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catena-Poly­[[bis­(ethyl­enedi­amine-κ2N,N′)copper(II)]-μ3-1,2-dicyanoethylenedi­thiolato-κ4N:S,S′:N′-[(1,2-dicyanoethylenedithiolato-κ2S,S′)­cuprate(II)]]

✍ Scribed by Fu, Ai-Yun ;Wang, Da-Qi ;Sun, De-Zhi

Publisher
International Union of Crystallography
Year
2004
Tongue
English
Weight
392 KB
Volume
60
Category
Article
ISSN
1600-5368

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📜 SIMILAR VOLUMES

Tris­(ethyl­enedi­amine-κ2N,N′)­cadmium(
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In the title complex, [Cd(C 2 H 8 N 2 ) 3 ][Cu(C 4 N 2 S 2 ) 2 ], the Cd II atom has a distorted octahedral geometry. The Cu II atom is in a distorted square-planar geometry. Both ions lie on twofold rotation axes. They are not connected covalently.

Bis­(ethyl­enedi­amine-κ2N,N′)(thio­sulf
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Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.005 A Ê R factor = 0.038 wR factor = 0.099 Data-to-parameter ratio = 14.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

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The title complex, [Zn(C 2 H 8 N 2 ) 3 ][Zn(C 4 N 2 S 2 ) 2 ], exists as discrete ions, both of which lie on twofold rotation axes. The [Zn(C 2 H 8 N 2 ) 3 ] 2+ cation exhibits a slightly distorted octahedral geometry. In the [Zn(C 4 N 2 S 2 ) 2 ] 2À anion, the Zn II atom is surrounded by two chelat