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cis-Diaqua­bis(1,10-phenanthroline)manganese(II) 4-sulfonatobenzoate 6.5-hydrate

✍ Scribed by Zhang, Li-Ping ;Zhu, Long-Guan ;Cai, Guo-Qiang


Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
170 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis


In the title complex salt, [Mn(C 12 H 8 N 2 ) 2 (H 2 O) 2 ](C 7 H 4 O 5 S)Á-6.5H 2 O, the coordination geometry about the Mn II atom is distorted octahedral, defined by four N atoms from two 1,10phenanthroline ligands and two O atoms from two water molecules. O-HÁ Á ÁO hydrogen-bonding interactions among cations, anions, and solvent water molecules generate a threedimensional network and enhance the stability of the crystal structure.


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