In the title complex, [Ni(C 12 H 8 N 2 ) 2 (H 2 O) 2 ](C 7 H 4 O 6 S)Á4H 2 O, the cation interacts with the anion and uncoordinated water molecules through hydrogen bonding with the coordinated water molecules, giving rise to a hydrogen-bonded sheet architecture. In the cation, the Ni atom exists in
cis-Diaquabis(1,10-phenanthroline)manganese(II) 4-sulfonatobenzoate 6.5-hydrate
✍ Scribed by Zhang, Li-Ping ;Zhu, Long-Guan ;Cai, Guo-Qiang
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 170 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title complex salt, [Mn(C 12 H 8 N 2 ) 2 (H 2 O) 2 ](C 7 H 4 O 5 S)Á-6.5H 2 O, the coordination geometry about the Mn II atom is distorted octahedral, defined by four N atoms from two 1,10phenanthroline ligands and two O atoms from two water molecules. O-HÁ Á ÁO hydrogen-bonding interactions among cations, anions, and solvent water molecules generate a threedimensional network and enhance the stability of the crystal structure.
📜 SIMILAR VOLUMES
metal-organic papers m106 Xie, He, Zhou andZhu [Co(C 8 H 4 NO) 2 (C 12 H 8 N 2 )(H 2 O) 2 ] Acta Cryst. (2004). E60, m105±m107
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.007 A Ê R factor = 0.048 wR factor = 0.099 Data-to-parameter ratio = 15.5 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.