cis-Diaquabis(1,10-phenanthroline)manganese(II) 3-carboxylato-4-hydroxybenzenesulfonate tetrahydrate
✍ Scribed by Fan, Sai-Rong ;Zhu, Long-Guan ;Xiao, Hong-Ping ;Ng, Seik Weng
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 223 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
In the title polymeric structure, {[Mn(C 8 H 3 NO 6 )(C 12 H 8 N 2 )]Á-H 2 O} n , the Mn atom adopts an octahedral geometry. The 2nitrobenzene-1,4-dicarboxylate ligand is in a chelating-bridging mode and its two carboxylate groups are approximately perpendicular to each other. The crystal structure
Single-crystal X-ray study T = 295 K Mean (C-C) = 0.005 A R factor = 0.052 wR factor = 0.112 Data-to-parameter ratio = 15.1 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the title complex, [Ni(C 12 H 8 N 2 ) 2 (H 2 O) 2 ](C 7 H 4 O 6 S)Á4H 2 O, the cation interacts with the anion and uncoordinated water molecules through hydrogen bonding with the coordinated water molecules, giving rise to a hydrogen-bonded sheet architecture. In the cation, the Ni atom exists in
Single-crystal X-ray study T = 295 K Mean '(C±C) = 0.013 A Ê R factor = 0.074 wR factor = 0.195 Data-to-parameter ratio = 11.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the title complex salt, [Mn(C 12 H 8 N 2 ) 2 (H 2 O) 2 ](C 7 H 4 O 5 S)Á-6.5H 2 O, the coordination geometry about the Mn II atom is distorted octahedral, defined by four N atoms from two 1,10phenanthroline ligands and two O atoms from two water molecules. O-HÁ Á ÁO hydrogen-bonding interactions