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Aqua­bis(2,2′-bi­pyridine)(3-carboxyl­ato-4-hydroxy­benzene­sulfonato)­manganese(II) dihydrate

✍ Scribed by Fan, Sai-Rong ;Zhu, Long-Guan ;Xiao, Hong-Ping ;Ng, Seik Weng

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
252 KB
Volume
61
Category
Article
ISSN
1600-5368

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Single-crystal X-ray study T = 295 K Mean (C-C) = 0.005 A R factor = 0.052 wR factor = 0.112 Data-to-parameter ratio = 15.1 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

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The Cu atom in the title compound, [Cu(C 7 H 5 O 6 S)-(C 10 H 8 N 2 )](C 7 H 5 O 6 S), is chelated by the two N-heterocycles and is covalently bonded to the sulfonate O atom of the sulfosalicylate ion in a trigonal±bipyramidal geometry. The uncoordinated sulfosalicylate anion interacts with adjacent