Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.002 A Ê R factor = 0.026 wR factor = 0.071 Data-to-parameter ratio = 12.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
cis-Dibromobis(1,10-phenanthroline)manganese(II)
✍ Scribed by Shen, Xiao-Ping ;Yuan, Ai-Hua
- Publisher
- International Union of Crystallography
- Year
- 2004
- Tongue
- English
- Weight
- 371 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.007 A Ê R factor = 0.048 wR factor = 0.099 Data-to-parameter ratio = 15.5 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 298 K Mean (C±C) = 0.009 A Ê R factor = 0.075 wR factor = 0.153 Data-to-parameter ratio = 12.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the title compound, [Mn(NCO) 2 (C 12 H 8 N 2 ) 2 ], the Mn atom, on a twofold rotation axis, is chelated by the two phenanthroline ligands, with two cyanate groups in cis positions.
In the title complex salt, [Mn(C 12 H 8 N 2 ) 2 (H 2 O) 2 ](C 7 H 4 O 5 S)Á-6.5H 2 O, the coordination geometry about the Mn II atom is distorted octahedral, defined by four N atoms from two 1,10phenanthroline ligands and two O atoms from two water molecules. O-HÁ Á ÁO hydrogen-bonding interactions