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Poly[[diaqua­bis(1,10-phenanthroline)bis­(μ3-5-sulfonatosalicylato)tricopper(II)] tetra­hydrate]

✍ Scribed by Fan, Sai-Rong ;Zhu, Long-Guan

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
169 KB
Volume
61
Category
Article
ISSN
1600-5368

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✍ Chen, Jian-Mei ;Fan, Sai-Rong ;Zhu, Long-Guan 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 262 KB

In the title complex, [Ni(C 12 H 8 N 2 ) 2 (H 2 O) 2 ](C 7 H 4 O 6 S)Á4H 2 O, the cation interacts with the anion and uncoordinated water molecules through hydrogen bonding with the coordinated water molecules, giving rise to a hydrogen-bonded sheet architecture. In the cation, the Ni atom exists in

Aqua­bis(1,10-phenanthroline)(3-sulfonat
Aqua­bis(1,10-phenanthroline)(3-sulfonatobenzoato)manganese(II) tetra­hydrate
✍ Yang, Teng-Jiao ;Xiao, Hong-Ping ;Zhu, Long-Guan 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 196 KB

The title compound, [Mn(C~7~H~4~O~5~S)(C~12~H~8~N~2~)~2~(H~2~O)]·4H~2~O, which was obtained by the reaction of MnCl~2~ with sodium hydrogen 3-sulfobenzoate and 1,10-phenanthroline, is a monomer. The coordination polyhedron of the Mn atom is a distorted octahedron. π–π Interactions between neighborin