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cis-Bis(benzylmethylphenylphosphine-κP)tetracarbonylmolybdenum(0)

✍ Scribed by Doddi, Adinarayana ;Luiz, T. Arun ;Ramkumar, V. ;Rao, M. N. Sudheendra

Publisher: International Union of Crystallography
Year: 2007
Tongue: English
Weight: 951 KB
Volume: 63
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536807048982

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✦ Synopsis

In the title compound, [Mo(CO)~4~(C~14~H~15~P)~2~], the molybdenum center has a slightly distorted cis-MoP~2~C~4~ octahedral geometry. One of the phosphine ligands is disordered over two orientations in a 0.686 (3):0.314 (3) ratio. The packing may be stabilized by weak C—H...O and C—H...π interactions.

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