Cis, anti, cis-Tricyclo[5.3.0.02,6]deca-4,9-dione

✍ Scribed by Arnon Shani; Zeev Tashma

• Book ID: 102858370
• Publisher: John Wiley and Sons
• Year: 1977
• Tongue: German
• Weight: 588 KB
• Volume: 60
• Category: Article
• ISSN: 0018-019X
• DOI: 10.1002/hlca.19770600609

✦ Synopsis

Abstract

The chemical behavior and some physical properties (dipole moment, IR. vs. Raman spectra) of the titled compound are not fully consistent with a strictly centrosymmetric structure which might be expected for the anti configuration. The carbonyl groups are less reactive toward nucleophilic reagents and sp^2^ → sp^3^ transformations as compared to cyclopentanone systems.