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Tricyclo[5.3.0.02,8]deca-3,5,9-triene

✍ Scribed by Dressel, Juergen; Paquette, Leo A.


Book ID
126419057
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
254 KB
Volume
109
Category
Article
ISSN
0002-7863

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The title compound (3), a molecule whose central cyclobutane ring is 1,3-bonded in hybrid fashion to two butadiene units, has been prepared and its thermal stability assessed relative to 1 and 2. The recently completed syntheses of l\* and 23 has permitted detailed analysis of the extent to which th

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## Abstract The chemical behavior and some physical properties (dipole moment, IR. __vs. Raman__ spectra) of the titled compound are not fully consistent with a strictly centrosymmetric structure which might be expected for the __anti__ configuration. The carbonyl groups are less reactive toward nu