Structure of cis-tricyclo[6.3.0.02,8]undecane-3,11-dione
โ Scribed by Kashino, S. ;Kimura, M. ;Kohara, S. ;Honjyo, M. ;Hirata, T. ;Kajifusa, N. ;Morosawa, S. ;Haisa, M.
- Book ID
- 114505317
- Publisher
- International Union of Crystallography
- Year
- 1988
- Tongue
- English
- Weight
- 319 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0108-2701
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1998 structure structure (organic substances) K 9000 ## 16 -042 cis-anti-cis-Tricyclo[6.4.0.0 2,7 ]dodecane-3,12-dione and cis-anti-cis-Tricyclo[6.4.0.0 2,7 ]dodecane-3,9-dione. -Single-crystal X-ray analysis of both photochemical products of 2-cyclohexenone, tricyclic title compounds (I) and (II
## Abstract The chemical behavior and some physical properties (dipole moment, IR. __vs. Raman__ spectra) of the titled compound are not fully consistent with a strictly centrosymmetric structure which might be expected for the __anti__ configuration. The carbonyl groups are less reactive toward nu