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Chirality transfer in the [2,3] Wittig rearrangement

โœ Scribed by Marshall, James A.; Jenson, Todd


Book ID
126834024
Publisher
American Chemical Society
Year
1984
Tongue
English
Weight
858 KB
Volume
49
Category
Article
ISSN
0022-3263

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Strict base dependence of chirality tran
โœ Toshiyuki Itoh; Kazutoshi Kudo ๐Ÿ“‚ Article ๐Ÿ“… 2001 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 84 KB

Investigation of [2,3]-Wittig rearrangement of optically active 1,1,2-trifluoroallylic ether revealed that chirality transfer of the starting compound strictly depended on the base employed, while stereoselectivity of the newly formed olefinic part was controlled with perfect (E)-selectivity. Becaus