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Asymmetric [2,3]-Wittig Rearrangement Induced by a Chiral Carbanion Whose Chirality Was Transferred from an Epoxide

✍ Scribed by Sasaki, Michiko; Higashi, Mariko; Masu, Hyuma; Yamaguchi, Kentaro; Takeda, Kei

Book ID: 127317847
Publisher: American Chemical Society
Year: 2005
Tongue: English
Weight: 57 KB
Volume: 7
Category: Article
ISSN: 1523-7060
DOI: 10.1021/ol052544h

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Enantioselective [2,3]-Wittig Rearrangement Induced by Asymmetric Lithiation with a t-Butyllithium / Chiral Bis(oxazoline) System. -The use of a chiral bis(oxazoline) is effective as ligand for the enantioselective [2,3]-Wittig rearrangement of (E)-and (Z)-propargyl ethers. -(TOMOOKA,