𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Chiral Catalyst Controlled Diastereoselection and Regioselection in Intramolecular Carbon−Hydrogen Insertion Reactions of Diazoacetates

✍ Scribed by Doyle, Michael P.; Kalinin, Alexey V.; Ene, Doina G.


Book ID
120565240
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
568 KB
Volume
118
Category
Article
ISSN
0002-7863

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


ChemInform Abstract: Chiral Catalyst Con
✍ M. P. DOYLE; A. V. KALININ; D. G. ENE 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 29 KB 👁 1 views

The individual enantiomers of substituted cyclohexyl diazoacetates (I)-(IV) or 2-octyl diazoacetates (V) matched with a configurationally suitable chiral dirhodium(II) carboxamidate catalyst provide an effective methodology for the synthesis of lactones with exceptional diastereoand regiocontrol. Th