ChemInform Abstract: Chiral Catalyst Con
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M. P. DOYLE; A. V. KALININ; D. G. ENE
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Article
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2010
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John Wiley and Sons
⚖ 29 KB
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The individual enantiomers of substituted cyclohexyl diazoacetates (I)-(IV) or 2-octyl diazoacetates (V) matched with a configurationally suitable chiral dirhodium(II) carboxamidate catalyst provide an effective methodology for the synthesis of lactones with exceptional diastereoand regiocontrol. Th