𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Synthesis of pyrrolizidine bases by highly diastereoselective and regioselective catalytic carbon-hydrogen insertion reactions of chiral pyrrolidinediazoacetamides

✍ Scribed by Michael P. Doyle; Alexey V. Kalinin

Book ID
103407691
Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
243 KB
Volume
37
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

ChemInform Abstract: Chiral Catalyst Con
ChemInform Abstract: Chiral Catalyst Controlled Diastereoselection and Regioselection in Intramolecular Carbon-Hydrogen Insertion Reactions of Diazoacetates.
✍ M. P. DOYLE; A. V. KALININ; D. G. ENE πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 29 KB πŸ‘ 1 views

The individual enantiomers of substituted cyclohexyl diazoacetates (I)-(IV) or 2-octyl diazoacetates (V) matched with a configurationally suitable chiral dirhodium(II) carboxamidate catalyst provide an effective methodology for the synthesis of lactones with exceptional diastereoand regiocontrol. Th