ChemInform Abstract: Synthesis of Pyrrolizidine Bases by Highly Diastereoselective and Regioselective Catalytic Carbon-Hydrogen Insertion Reactions of Chiral Pyrrolidinediazoacetamides.
β Scribed by M. P. DOYLE; A. V. KALININ
- Book ID
- 112033015
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 29 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0931-7597
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π SIMILAR VOLUMES
The individual enantiomers of substituted cyclohexyl diazoacetates (I)-(IV) or 2-octyl diazoacetates (V) matched with a configurationally suitable chiral dirhodium(II) carboxamidate catalyst provide an effective methodology for the synthesis of lactones with exceptional diastereoand regiocontrol. Th
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