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Chemistry of propadiene. II. The addition of dichlorocarbene to propadiene

✍ Scribed by H. G. Peer; A. Schors

Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
287 KB
Volume
86
Category
Article
ISSN
0165-0513

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πŸ“œ SIMILAR VOLUMES

The chemistry of propadiene: Some invest
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## Abstract The reaction of propadiene with Br~2~, BrCl, and Cl~2~ is studied in various solvents and at different temperatures. It is shown that only partial addition takes place, and further that the initial attack of the Hal^+^ ion takes place at the central C atom. The findings are interpreted

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A recent reactivity comparison of dichlorocarbene and chlorofluorocarbene suggested that steric hindrance played an important role in determining the rate of the carbene-olefin addition reaction (1). Indeed, although warnings were is-